ICS

17.200

CCS

A42

中華人民共和國國家標(biāo)準(zhǔn)

GB/T44234—2024

納米技術(shù)納米材料與氣體表界面作用

熱力學(xué)參數(shù)和動(dòng)力學(xué)參數(shù)測(cè)量

諧振微質(zhì)量法

Nanotechnology—Measurementofthermodynamicandkineticparametersof

interfaceinteractionbetweennanomaterialsandgases—Microgravimetric

analysismethod

2024-08-23發(fā)布2025-03-01實(shí)施

國家市場(chǎng)監(jiān)督管理總局發(fā)布

國家標(biāo)準(zhǔn)化管理委員會(huì)

GB/T44234—2024

目次

前言

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Ⅲ

引言

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Ⅳ

1

范圍

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1

2

規(guī)范性引用文件

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1

3

術(shù)語和定義

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1

4

符號(hào)

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2

5

方法原理

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3

5.1

諧振式微懸臂梁的工作原理

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3

5.2

熱力學(xué)參數(shù)與動(dòng)力學(xué)參數(shù)的計(jì)算

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3

6

儀器和設(shè)備

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4

6.1

測(cè)試裝置

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4

6.2

動(dòng)態(tài)配氣系統(tǒng)

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4

6.3

恒溫箱

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4

6.4

接口電路和控制系統(tǒng)

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5

6.5

諧振式微懸臂梁

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5

7

測(cè)試樣品和試劑

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5

7.1

測(cè)試樣品

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5

7.2

稀釋氣

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5

7.3

測(cè)試氣

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5

7.4

分散劑

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5

8

測(cè)試方法

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6

8.1

標(biāo)準(zhǔn)測(cè)試條件

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6

8.2

樣品涂覆

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6

8.3

樣品測(cè)試

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6

9

數(shù)據(jù)處理

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6

9.1

熱力學(xué)參數(shù)

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6

9.2

動(dòng)力學(xué)參數(shù)─活化能Ea

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8

10

測(cè)試報(bào)告

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8

附錄A（資料性）介孔納米顆粒材料吸附熱力學(xué)參數(shù)的測(cè)量實(shí)例

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9

附錄B（資料性）納米材料吸附動(dòng)力學(xué)參數(shù)的測(cè)量實(shí)例

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13

附錄C（資料性）測(cè)試報(bào)告格式

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16

參考文獻(xiàn)

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17

Ⅰ

GB/T44234—2024

前言

本文件按照GB/T1.1—2020《標(biāo)準(zhǔn)化工作導(dǎo)則第1部分：標(biāo)準(zhǔn)化文件的結(jié)構(gòu)和起草規(guī)則》的規(guī)

定起草。

請(qǐng)注意本文件的某些內(nèi)容可能涉及專利。本文件的發(fā)布機(jī)構(gòu)不承擔(dān)識(shí)別專利的責(zé)任。

本文件由中國科學(xué)院提出。

本文件由全國納米技術(shù)標(biāo)準(zhǔn)化技術(shù)委員會(huì)（SAC/TC279）歸口。

本文件起草單位：中國科學(xué)院上海微系統(tǒng)與信息技術(shù)研究所、國家納米科學(xué)中心、廈門海恩邁科技

有限公司、上海納米技術(shù)及應(yīng)用國家工程研究中心有限公司、同濟(jì)大學(xué)、中國計(jì)量科學(xué)研究院。

本文件主要起草人：李昕欣、許鵬程、于海濤、葛廣路、程鑫彬、何丹農(nóng)、任玲玲、朱君、金涵。

Ⅲ

GB/T44234—2024

引言

基于界面分子作用的功能納米材料，在信息獲取、生態(tài)環(huán)境、新能源和健康醫(yī)療等領(lǐng)域應(yīng)用十分廣

泛。本文件描述了一種利用諧振微懸臂梁作為核心測(cè)量工具的諧振微質(zhì)量法，目的是為納米材料與氣體

界面作用熱力學(xué)參數(shù)和動(dòng)力學(xué)參數(shù)的獲取提供一種標(biāo)準(zhǔn)的測(cè)量方法。該方法能夠有效避免傳統(tǒng)測(cè)量方法

的問題，獲得包括焓變、熵變、吉布斯自由能、活化能等在內(nèi)的熱力學(xué)參數(shù)和動(dòng)力學(xué)參數(shù)，兼顧科學(xué)研

究和產(chǎn)業(yè)應(yīng)用的需求。

Ⅳ

GB/T44234—2024

納米技術(shù)納米材料與氣體表界面作用

熱力學(xué)參數(shù)和動(dòng)力學(xué)參數(shù)測(cè)量

諧振微質(zhì)量法

1范圍

本文件描述了基于諧振微質(zhì)量法獲得納米材料與氣體界面作用熱力學(xué)參數(shù)和動(dòng)力學(xué)參數(shù)的方法，包

括方法原理、儀器和設(shè)備、測(cè)試樣品和試劑、測(cè)試方法、數(shù)據(jù)處理、測(cè)試報(bào)告。

本文件適用于熱力學(xué)參數(shù)與動(dòng)力學(xué)參數(shù)的測(cè)量，包括標(biāo)準(zhǔn)焓變（ΔH°）、標(biāo)準(zhǔn)熵變（ΔS°）、標(biāo)準(zhǔn)吉

布斯自由能變（ΔG°）、活化能（Ea）等。

2規(guī)范性引用文件

下列文件中的內(nèi)容通過文中的規(guī)范性引用而構(gòu)成本文件必不可少的條款。其中，注日期的引用文

件，僅該日期對(duì)應(yīng)的版本適用于本文件；不注日期的引用文件，其最新版本（包括所有的修改單）適用

于本文件。

GB/T2298—2010機(jī)械振動(dòng)、沖擊與狀態(tài)監(jiān)測(cè)詞匯

GB/T13464—2008物質(zhì)熱穩(wěn)定性的熱分析試驗(yàn)方法

GB/T21650.2—2008壓汞法和氣體吸附法測(cè)定固體材料孔徑分布和孔隙度第2部分：氣體吸

附