化工熱力學課后答案（第三版）陳鐘秀編著50℃的容器中產生的壓力1）理想氣體方程2）R-K方程3）cccrcrccrcrc法rrccci利用真實氣體混合物的第二維里系數法進行計算cijcicj-6)cijcijcijcijrijcijrijcijrijcijrijcij:B12EQ\*jc3\*hps34\o\al(\s\up9(RT),P)EQ\*jc3\*hps19\o\al(\s\up0(0),12)EQ\*jc3\*hps19\o\al(\s\up0(1),1))B-6)-6)-6)-63總mmcrcrcrr cccccEQ\*jc3\*hps28\o\al(\s\up14(8),45)EQ\*jc3\*hps28\o\al(\s\up14(3),8)EQ\*jc3\*hps28\o\al(\s\up14(44),59)EQ\*jc3\*hps28\o\al(\s\up14(6),10)EQ\*jc3\*hps28\o\al(\s\up14(8),0)EQ\*jc3\*hps28\o\al(\s\up14(9),9.458)rc2ccEQ\*jc3\*hps36\o\al(\s\up15(a),b)/rcBEQ\*jc3\*hps20\o\al(\s\up4(2),1)EQ\*jc3\*hps20\o\al(\s\up4(2),2)0.3n×28+0.7n×58=7→n=0.1429m3cc①①、②兩式聯立，迭代求解壓縮因子Zrc2r62.K0.56cc-5①、②兩式聯立，迭代求解壓縮因子Z①②得得(?x,y(?y,z(?z,x又又(?V,(?T,P,(?V,(?T,P,故93℃,反抗一恒定的外壓力3.45MPa而等溫膨脹，直到兩倍于其初pp下氯的焓、熵值。已知氯在理想氣體狀態(tài)下的定壓摩爾熱容為J/(mol.K)p21—真實氣體R1R2理想氣體理想氣體rrrrrrrrrEQ\*jc3\*hps14\o\al(\s\up0(R),2)rEQ\*jc3\*hps17\o\al(\s\up4(R),2)EQ\*jc3\*hps17\o\al(\s\up4(R),2)2EQ\*jc3\*hps19\o\al(\s\up7(R),1)EQ\*jc3\*hps18\o\al(\s\up5(R),2)H-V1VEQ\*jc3\*hps21\o\al(\s\up2(id),P)+ΔH+ΔHid+HRVEQ\*jc3\*hps20\o\al(\s\up2(R),2)EQ\*jc3\*hps20\o\al(\s\up2(R),2)蒸氣。兩個容器的體積均為1L，壓力都為1MPa。如果這兩炸，試問哪一個容器被破壞的更嚴重？假定A、B容器內物質做可逆g3/ggl3/gl根據題意液體和蒸汽各占一半體積，設干度為xJ/(mol.K)p∴c26cEQ\*jc3\*hps36\o\al(\s\up15(1),0)EQ\*jc3\*hps36\o\al(\s\up15(5),0)EQ\*jc3\*hps36\o\al(\s\up15(4),6)0ccip∵汽液平衡時，fL=fV=fSiiii又理想氣體的f=PiSiiiii=fiSPiS5iiggABp::EQ\*jc3\*hps20\o\al(\s\up0(2),2)EQ\*jc3\*hps20\o\al(\s\up0(3),2)EQ\*jc3\*hps20\o\al(\s\up0(4),2)(?V)2,EQ\*jc3\*hps21\o\al(\s\up5(2),2)EQ\*jc3\*hps21\o\al(\s\up5(3),2)(?V)EQ\*jc3\*hps18\o\al(\s\up2(2),2)EQ\*jc3\*hps18\o\al(\s\up2(3),2)EQ\*jc3\*hps18\o\al(\s\up2(4),2)EQ\*jc3\*hps18\o\al(\s\up2(2),2)EQ\*jc3\*hps18\o\al(\s\up2(3),2)EQ\*jc3\*hps20\o\al(\s\up1(2),2)EQ\*jc3\*hps20\o\al(\s\up1(3),2)EQ\*jc3\*hps20\o\al(\s\up1(4),2)EQ\*jc3\*hps17\o\al(\s\up1(2),2)EQ\*jc3\*hps17\o\al(\s\up1(3),2)EQ\*jc3\*hps17\o\al(\s\up1(4),2)EQ\*jc3\*hps17\o\al(\s\up1(2),2)EQ\*jc3\*hps17\o\al(\s\up1(3),2)EQ\*jc3\*hps20\o\al(\s\up1(2),2)EQ\*jc3\*hps20\o\al(\s\up1(3),2)EQ\*jc3\*hps20\o\al(\s\up1(4),2)溫度、壓力狀態(tài)下（1）用x表示的H和H2）純組分焓H和H的數值3）無限稀釋下液體的偏摩爾焓H∞和H∞的數值。（A）EQ\*jc3\*hps20\o\al(\s\up1(3),1)EQ\*jc3\*hps21\o\al(\s\up2(2),1)H1）（2VEQ\*jc3\*hps21\o\al(\s\up2(2),1)EQ\*jc3\*hps21\o\al(\s\up2(2),2)得或EQ\*jc3\*hps29\o\al(\s\up3(?),φ)EQ\*jc3\*hps29\o\al(\s\up3(?),φ)ccccEQ\*jc3\*hps23\o\al(\s\up11(2T),P)EQ\*jc3\*hps23\o\al(\s\up11(2),1)2ijiaj)ij)EQ\*jc3\*hps20\o\al(\s\up4(2),1)EQ\*jc3\*hps20\o\al(\s\up4(2),2)22im①①②②∴EQ\*jc3\*hps20\o\al(\s\up2147483647(E),1)EQ\*jc3\*hps20\o\al(\s\up2147483647(E),2)xEQ\*jc3\*hps36\o\al(\s\up4(^),f)EQ\*jc3\*hps36\o\al(\s\up4(^),f)EQ\*jc3\*hps36\o\al(\s\up4(^),f)EQ\*jc3\*hps36\o\al(\s\up4(^),f)EQ\*jc3\*hps21\o\al(\s\up0(2),2)EQ\*jc3\*hps21\o\al(\s\up0(2),2)lny2EQ\*jc3\*hps21\o\al(\s\up0(2),1)EQ\*jc3\*hps21\o\al(\s\up0(2)